PEROXIDE

PEROXIDE


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Product name PEROXIDE Certification -
Category Dyestuffs Ingredients -
Keyword - Unit Size -
Brand name - Unit Weigh -
origin Stock -
Supply type - HS code -

Product Information

* For more information, click product name.  
ALKENOX-P100        
 
ALKENOX P-100
Summary
ALKENOX P-100 is a white fine powder which has peroxy group in the molecular. It is generally used for initiator of polymerization in the unsaturated polyester resin, vinyl chloride
mono-polymerization & Copol ymerization.
Formula
- Formula :

- Name : Bis-(4-tert-butylcyclohexyl)
              Peroxy dicarbonate
- CAS No : 15520-11-3
- Molecular weight : 398.64
 
Pyhsical Properity
- Appearance : White fine power
- Purity : Min. 95%
- Molecular weight : 398.64
- Temperature at 10 hrs half life : 44℃
- Activation energy : 30.2kcal / mol
- Solubility : insoluble in water,
- Soluble in Ketones, Esters, Aromatic
   Hydrocarbon
Chemical Prooerity

- Strong oxidation agent.
- Active oxygen content : Min 3.8%
- Heat decomposition properties Half life of
   ALKENOX P-100 at 0.2 mol/mol in benzene

Temp (℃)

Half life(hours)

 40

17.4

44

10

 50

4

 60

1

 92

1

- Flash point : Room temperature
- Combustion properties (sample 10g)
  Burning time : 5 sec
  Flame length : 100㎝  
 
Decomposition Compound
 ALKENOX P-100 is easy to decompose by hea The Mechanism of decomposition.
Safety Test
- Ignition temp. : Room temp
- Auto lgnition temp : 360℃
- Combustion properties (sample 10g)
  Combustion time : 5 sec   
  Length of flame : 100 sec   
  Drop-hammer sensitivity : 30Cm
  Pressure test : Max.0.7mm
 
Package
- Inner package : Polyethylene bag
- Ourter package : Craft paper box
Application

-The initiator of unsaturated polyester resin
ALKENOX P-100 has low decomposing temp(44
).  It is suitable for pulltrusion mold, continuous laminating and large scale mold. Especially large scale moding, heating furnace is needed to get a high temperature. ALKENOX P-100 which has low decomposing temp is suitable for that cases. ALKENOX P-100 is also used with other curing agent such as BPO(Benzoxl peroxide), TBPB(t-butyl-perbenzoate) and other metal salt accelerators. In that case, we can expect a improved properties after curing.

- Polymerization initiator of VCM(Vinyl Chloride Monomer)  
ALKENOX P-100 is used for polymerization of VCM which is the monomer of PVC at 40~70


- Polymerization initiator of other monomer
ALKENOX P-100 is used as initiator of homopolymer
- ization & copolymerization of acrylate,  methacrylate

ane vinylidene floride monomer-
Storage and Handling

The test report of storage safety of ALKENOX P-100

Period of storage Decrease rate of active oxygen

30℃

40℃

1 week

-

1.5%

2 weeks

1.3%

2.6%

3 weeks

-

4.6%

4 weeks

1.3%

-

5 weeks

-

7.4%

6 weeks

2%

13%

7 weeks

3%

-

11 weeks

4.3%

-

24 weeks

6.4%

-

- Storage
   ALKENOX P-100 is quite active peroxide. However handling it at room temperature is possible as it's storage stability at room temperature is a rather high so it is possible to handle at room temperature.    But it can be decompesed at above 25
, so it must be stored under 20 and kept away from direct sunligiht

- First aid
   Skin contact cause a hazard like other peroxides, so appropriate protection is needed. During working, protective clothes and protective hand cream is needed.
---Eye Contact : Immediately flush eyes with plenty of water.                                          
Get medical attention immddiatly

---Skin Contact : Immediately flush skin with   plenty of soap and water. Get medical  attention immediately.

---Ingestion : Not to vomit. Get medical attention
- Toxicological information
   Oral rat : LD 50 : >5g/

Appendix
- Solublity Data (wt% conc)

Solvents

-20℃

0℃

10℃

20℃

30℃

Methanol

-

1

-

-

2.3

Hentane

-

7.5

-

-

17.5

 Shellsol T

-

2

-

4.04

-

 Shellsol K

-

-

-

5

-

MEK

11

24.7

-

-

31.4

MIBK

-

17.5

-

-

31.3

Benzene

-

29.3

46.7

-

49.3

Tpluene

-

33

-

-

49

MeAc

-

11.5

-

-

22.2

FtAc

-

16

-

-

32

Dibuth Phthalate

-

9.2

-

11.8

14.1

CCI4

-

19

-

-

21.5

Ethylene

-

-

-

-

-

teichloride

11

24.5

-

33

-

Viryl

-

-

-

-

-

Chloride

15

25

-

-

-

MMA

-

19.8

-

25

-

- Curing Properties & Pot life of curing agent

Initiator

Criti Cal Temp
(℃)

80℃

Pot Life
(hrs)

G.T (min

C.T (min

T.max (℃)

Hard
ness

30℃

40℃

ALKENOXP-100

 50

0.6

1.1

231

47

10

3

Kayanox

 

1.6

2.8

209

42

3

1

Laubox

 

3

4.1

204

44

35

8

Trigonox 38

65

4

11.3

173

42

9

3

BPO

70

5.9

7.3

203

44

50

14

t-butyl perhenzoate

70

3.7

5.2

222

48

27

8

 Trigonox 29~75%

70

8.4

10.7

200

47

70

22

Kayacarhon BIC-75 

 70

16.9

26.2

193

45

40

18

 Kayanox A-M

80

3.3

6.3

197

43

70

3

Initiator

Criti Cal
Temp (℃)

100℃

Pot Life (hrs)

G.T (min)

C.T (min)

T.max (℃)

Hard
ness

30℃

40℃

ALKENOXP-100

 50

-

-

-

-

10

3

Kayanox

 

0.2

0.6

226

43

3

1

Laubox

 

0.3

0.7

210

45

35

8

Trigonox 38

65

1.5

2.9

229

46

9

3

BPO

70

1

15

248

47

50

14

t-butyl perhenzoate

70

0.2

0.5

223

50

27

8

 Trigonox 29~75%

70

1.6

2.3

222

48

70

22

Kayacarhon BIC-75 

 70

2.9

4.2

237

45

40

18

 Kayanox A-M

80

0.8

0.8

226

4.

70

3

※  Test Condition : JISK 6901, use unsaturated
      polyester resin lnitiator : 1phr
- The combination of ALKENOXP-100 & other  initiator
  t-butyl perhenzoate

Using amount(phr)

80℃ Curing

Pot life (hrs)

ALKENOX P-100

t-butyl perhenzoate

G.T (min)

C.T (min)

T.max (℃)

Hard ness

0

1

3.8

5.2

222

45

26

0.2

0.8

2

2.9

224

45

16

0.5

0.5

1

1.6

221

45

11

0.8

0.2

0.6

1.2

223

45

9

1

0

0.5

0.9

226

45

8

  BPO

Using amount(phr)

80℃ Curing

Pot life (hrs)

ALKENOX P-100

t-butyl perhenzoate

G.T (min)

C.T (min)

T.max (℃)

Hard ness

0

1

5.9

7.3

220

45

4~5

0.2

0.8

2.4

3.3

222

45

27

0.5

0.5

1

1.7

225

45

13

0.8

0.2

0.6

1.2

223

45

9

1

0

0.5

0.5

226

45

8

 

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Price (FOB) Negotiable transportation -
MOQ Negotiable Leadtime Negotiable
Payment Options Negotiable Shipping time Negotiable

FTC Korea

Country / Year Established
South Korea South Korea /
Business type
Others

16

TRADE TOWER

DUNS

President
Ma Younghun
Address
982 Yongso-ri, Yanggam-myun, Hwasung-si, Gyeonggi-do, Korea
Product Category
Dyestuffs,Other Chemicals
Company introduction

We were established in Sept. 1999, capitalized at USD450,000.00 with annual sales turnover USD5Million fiscal year 2007, we have been a specialty chemicals manufacturer (ISO9001 accredited manufacturer & trader) to produce paint catalysts of acid/blocked/tin/polymerization, anti-foaming de-aerating agents, leveling agents, anti-flooding & pigment dispersing agents, Rheology control agents, functional epoxy/polyester/acrylic resins, etc. for Coil coating, Industrial coating and Automotive painting applications.

For your reference, I would like to inform you that FTC is conducting branch corp. from 2004 in Shanghai China and also we want you to refer that we have supplied our paint catalyst & levelling agent matching for King Industries & BYK to Shanghai Chen Hua Paint Manufacturing Co. who is the largest local paint manufacturer in China, regularly together with other 4~5 Clients annual total about 60MTY, and several Paint manufacturing Corporations invested from Korea, such as Samhwa Paint Co., Ltd., Kumgang Chemical Corp.(KCC), Daehan Paint Industries(DPI), Dongshin Paint Co., Ltd. in annual total 200MTY. On the other hand, we have also supplied our paint catalyst & additives to Vietnamese Clients from last year, and are planning to positively promote World market especially in North America, Europe, China, India, Indonesia, etc. from the second half of this year.

At the height of "2nd wave era of Globalization" publicated from IMD Switzerland this year, we are seriously looking for new reliable megalopolitan sales agent or future Client to enable us meet custom made marketing throughout the World.

Any query or questionnaire is available on Click Inquire Now.

Main Markets

China China

Hong Kong(China) Hong Kong(China)

Viet Nam Viet Nam

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